Enantioselective desymmetrizing palladium catalyzed carbonylation reactions: the catalytic asymmetric synthesis of quaternary carbon center containing 1,3-dienes.
نویسندگان
چکیده
A desymmetrization protocol has been used to develop a palladium catalyzed enantioselective carbonylation process. Achiral cyclic bis-alkenyltriflates are converted to their corresponding monoester derivatives with selectivities of up to 96% ee.
منابع مشابه
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 8 4 شماره
صفحات -
تاریخ انتشار 2010